EPSRC Funded Postdoctoral Research Associate Position Available

Applications are invited for an EPSRC funded research associate role with Dr Tom Oliver in the Laser Chemistry, Spectroscopy and Dynamics Group in the School of Chemistry at the University of Bristol. This project involves a close collaboration with Dr Mike Jones in the School of Biochemistry. The appointee will use state-of-the-art multidimensional optical spectroscopies to explore inter-pigment electronic energy transfer dynamics in bacterial reaction centres.

Applicants should have, or be about to graduate with a Ph.D. in Chemistry, Chemical Physics, or a related discipline. Candidates should have proven experience with at least some of the following: laser spectroscopy, ultrafast laser technology and non-linear optics.

This 1 year position is available from 1st January 2017.

The research associate will also be expected to assist in supervising PhD students in the research group of Dr. Tom Oliver. Informal enquiries may be addressed to: tom.oliver@bristol.ac.uk.

The full job description can be found here and applications made here.

PhD Vacancy

Unravelling Energy and Charge Transport Mechanisms in Natural Light Harvesting and Photovoltaic Materials

A fully funded PhD position is available in the Oliver group with a standard EPSRC stipend of £14,296 for 2016/2017.

Photosynthetic organisms harness energy from sunlight to power most biological activity on Earth. Inside chloroplasts of plants, sunlight is absorbed by billions of chlorophyll molecules and used to drive photosynthesis; carbon dioxide and water are converted into simple sugars essential for plant growth. This remarkable natural process regularly achieves 100% efficiency: every photon absorbed is converted into chemical energy. Our efforts to harness solar energy with man-made photovoltaic (PV) technology to generate electricity have, to date, been far less effective. To meet the ever-growing global energy demands, it is imperative for our society to develop renewable and more efficient PV devices that can take full advantage of the abundant solar flux.

This project will use cutting-edge ultrafast laser spectroscopies such as two-dimensional electronic-vibrational spectroscopy [1] and 2D electronic spectroscopy [2], to follow create a map of energy/charge flow between molecules with femtosecond time resolution (1 fs = one millionth billionth of a second) in natural light harvesting proteins, biomimetic counterparts and leading PV materials such as perovskites, quantum dots and organic bulk heterojunction polymers.

By understanding the routes and timescales of energy flow inside natural light harvesting systems and PV materials, we will seek to gain a fundamental understanding on the molecular level of the mechanisms that underpin energy transport and charge-separation. These insights will provide (1) a greater fundamental understanding of natural light harvesting and (2) a guide to the design of the next-generation thin film PV materials.

This project involves strong collaborations with Dr Mike Jones, Dr Ross Anderson (School of Biochemistry), and Professor David Fermin (School of Chemistry) at the University of Bristol.

[1] TAA Oliver, NHC Lewis and GR Fleming, Proc. Natl. Acad. Sci., 111, 10061 (2014).
[2] VM Huxter, TAA Oliver, D Budker and GR Fleming, Nat. Physics., 9, 744 (2013).

For more project details and informal enquiries contact Dr Tom Oliver: tom.oliverATbristol.ac.uk

Rutherford Appleton Laboratory Laser Time Granted

epstMy project to study the ultrafast relaxation pathways of anthocyanins has been granted laser time at the Rutherford Appleton Laboratory.

Higher plants have an extremely sophisticated suite of photoprotective mechanisms that prevent damage in high light conditions. Mechanisms involving anthocyanin molecules have to date received little attention, despite comprising 50% of pigments in leaves during the Autumnal period.

Anthocyanins such as malvin, cyanin and pelargonin are thought to provide a sunscreen to chlorophyll containing proteins, absorbing any excess light in the blue-green part of the solar spectrum, and dissipating this excess energy harmlessly.

Our study will seek to determine whether non-radiative decay of anthocyanin molecules are driven by excited state or ground state proton transfer.